NILE
CHEMICALS
NILE
CHEMICALS
1.
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product
name : 3-Nitroaniline
2.
HAZARDS IDENTIFICATION
Classification
of the substance or mixture
According
to Regulation (EC) No1272/2008
Acute
toxicity (Category 3)
Acute
toxicity (Category 3)
Acute
toxicity (Category 3)
Specific
target organ toxicity - repeated exposure (Category 2)
Chronic
aquatic toxicity (Category 3)
According
to European Directive 67/548/EEC as amended.
Toxic
by inhalation, in contact with skin and if swallowed. Danger of cumulative
effects. Harmful to aquatic
organisms,
may cause long-term adverse effects in the aquatic environment.
Other
hazards - none
3.
COMPOSITION/INFORMATION ON INGREDIENTS
Formula
: C6H6N2O2
Molecular
Weight : 138,12 g/mol
CAS-No.
EC-No. Index-No. Classification Concentration
4.
FIRST AID MEASURES
General
advice Consult a physician. Show this
safety data sheet to the doctor in attendance.
If
inhaled If breathed in, move person into
fresh air. If not breathing, give artificial respiration. Consult a physician.
In
case of skin contact Wash off with soap and
plenty of water. Take victim immediately to hospital. Consult a physician.
In
case of eye contact Flush eyes with water
as a precaution.
If
swallowed Never give anything by mouth to
an unconscious person. Rinse mouth with water. Consult a physician.
5.
FIRE-FIGHTING MEASURES
Suitable
extinguishing media Use water spray,
alcohol-resistant foam, dry chemical or carbon dioxide.
Special
protective equipment for fire-fighters Wear
self contained breathing apparatus for fire fighting if necessary.
6.
ACCIDENTAL RELEASE MEASURES
Personal
precautions Wear respiratory protection.
Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate
ventilation.
Evacuate personnel to safe areas. Avoid breathing dust.
Environmental
precautions Prevent further leakage or
spillage if safe to do so. Do not let product enter drains. Discharge into the
environment
must be avoided.
Methods
and materials for containment and cleaning up Pick
up and arrange disposal without creating dust. Sweep up and shovel. Keep in
suitable, closed containers for disposal.
7.
HANDLING AND STORAGE
Precautions
for safe handling Avoid contact with skin
and eyes. Avoid formation of dust and aerosols.
Provide
appropriate exhaust ventilation at places where dust is formed. Normal measures
for preventive fire
protection.
Conditions
for safe storage Keep container tightly
closed in a dry and well-ventilated place. Store in cool place.
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal
protective equipment
Respiratory
protection Where risk assessment shows
air-purifying respirators are appropriate use a full-face particle respirator
type
N99 (US) or type P2 (EN 143) respirator cartridges as a backup to engineering
controls. If the
respirator
is the sole means of protection, use a full-face supplied air respirator. Use
respirators and
components
tested and approved under appropriate government standards such as NIOSH (US) or
CEN
(EU).
Hand
protection Handle with gloves. Gloves must
be inspected prior to use. Use proper glove removal technique (without
touching
glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves
after
use in accordance with applicable laws and good laboratory practices. Wash and
dry hands.
The
selected protective gloves have to satisfy the specifications of EU Directive
89/686/EEC and the
standard
EN 374 derived from it.
Eye
protection Face shield and safety glasses
Use equipment for eye protection tested and approved under appropriate
government
standards such as NIOSH (US) or EN 166(EU).
Skin
and body protection Complete suit
protecting against chemicals, The type of protective equipment must be selected
according
to
the concentration and amount of the dangerous substance at the specific
workplace.
Hygiene
measures Avoid contact with skin, eyes and
clothing. Wash hands before breaks and immediately after handling the
product.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form crystalline
Colour
yellow
Safety
data
pH
no data available
Melting
point 111 - 114 °C - lit.
Boiling
point 306,0 °C
Flash
point 196,0 °C - closed cup
Ignition
temperature no data available
Lower
explosion limit no data available
Upper
explosion limit no data available
Density
0,90 g/cm3 at 25,00 °C
Water
solubility no data available
10.
STABILITY AND REACTIVITY
Chemical
stability Stable under recommended storage
conditions.
Conditions
to avoid no data available
Materials
to avoid acids, Acid chlorides, Acid
anhydrides, Chloroformates, Strong oxidizing agents
Hazardous
decomposition products
Hazardous
decomposition products formed under fire conditions. - Carbon oxides, nitrogen
oxides (NOx)
11.
TOXICOLOGICAL INFORMATION
Acute
toxicity LD50 Oral - rat - 535,0 mg/kg
Skin
corrosion/irritation no data available
Serious
eye damage/eye irritation no data available
Respiratory
or skin sensitization no data available
Germ
cell mutagenicity no data available
Carcinogenicity
IARC: No component of this product present
at levels greater than or equal to 0.1% is identified as
probable,
possible or confirmed human carcinogen by IARC.
Reproductive
toxicity no data available
Specific
target organ toxicity - single exposure no
data available
Specific
target organ toxicity - repeated exposure no
data available
Aspiration
hazard no data available
Potential
health effects Inhalation Toxic if inhaled.
May cause respiratory tract irritation.
Ingestion
Harmful if swallowed.
Skin
Toxic if absorbed through skin. May cause
skin irritation.
Eyes
May cause eye irritation.
Signs
and Symptoms of Exposure Absorption into
the body leads to the formation of methemoglobin which in sufficient
concentration causes
cyanosis.
Onset may be delayed 2 to 4 hours or longer., To the best of our knowledge, the
chemical, physical,
and
toxicological properties have not been thoroughly investigated.
Additional
Information RTECS: BY6825000
12.
ECOLOGICAL INFORMATION
Toxicity
Toxicity
to fish LC50 - other fish - 81,2 mg/l - 96,0 h
Toxicity
to daphnia
and
other aquatic
invertebrates.
EC50
- Daphnia magna (Water flea) - 0,19 - 2,02 mg/l - 48 h
Toxicity
to algae EC50 - No information available. - 28,00 - 58,00 mg/l - 72 h
Persistence
and degradability
Bioaccumulative
potential
Bioaccumulation
Danio rerio (zebra fish) - 96
h
Bioconcentration
factor (BCF): 8,3
Mobility
in soil
no
data available
PBT
and vPvB assessment
no
data available
Other
adverse effects
Very
toxic to aquatic life.
13.
DISPOSAL CONSIDERATIONS
Product
Offer surplus and non-recyclable solutions
to a licensed disposal company. Contact a licensed professional
waste
disposal service to dispose of this material. Dissolve or mix the material with
a combustible solvent
and
burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated
packaging
Dispose
of as unused product.
14.
TRANSPORT INFORMATION
ADR/RID
UN-Number:
1661 Class: 6.1 Packing group: II
Proper
shipping name: NITROANILINES
IMDG
UN-Number:
1661 Class: 6.1 Packing group: II EMS-No: F-A, S-A
Proper
shipping name: NITROANILINES
Marine
pollutant: No
IATA
UN-Number:
1661 Class: 6.1 Packing group: II
Proper
shipping name: Nitroanilines
15.
REGULATORY INFORMATION
This
safety datasheet complies with the requirements of Regulation (EC) No.
1907/2006.
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