NILE CHEMICALS

BISMUTH AMMONIUM CITRATE

 

Section 1: Chemical Product and Company Identification

Product Name: Bismuth Ammonium Citrate Extra Pure

CAS#: 31886-41-6

Synonym: Ammonium Ferric Citrate; Ammonium iron (III) citrate; Iron (III) ammonium citrate; 1,2,3-Propanetricarboxylic acid, 2-hydroxy, ammonium iron (3+) salt

Chemical Name: Citric Acid, ammonium iron (3+) salt

Chemical Formula: This compound is a complex salt of undetermined structure, composed of Iron, Ammonia, and Citric Acid

 

Section 2: Composition and Information on Ingredients Composition:

Name CAS # % by Weight

Bismuth Ammonium Citrate Extra Pure 31886-41-6 100

Toxicological Data on Ingredients: Not applicable.

 

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.

Potential Chronic Health Effects:

Slightly hazardous in case of skin contact (irritant).

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available.

 

Section 4: First Aid Measures Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.

Skin Contact:Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water may be used.

Serious Skin Contact: Not available.

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Serious Inhalation: Not available.

Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight                                                                                                                                                                                                  clothing such as a collar, tie, belt or waistband.

Serious Ingestion: Not available.

 

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks, of heat.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available.  Slightly explosive in presence of heat.

Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder.

LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Toxic oxides of nitrogen or ammonia gas may be formed in fires.

Special Remarks on Explosion Hazards: Containers may explode when heated.

 

Section 6: Accidental Release Measures Small Spill:

Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.

Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

 

Section 7: Handling and Storage

Precautions: Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe dust.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Sensitive to light. Store in light-resistant containers.

 

Section 8: Exposure Controls/Personal Protection Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.

Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

Exposure Limits: TWA: 1 STEL: 2 (mg(Fe)/m) [United Kingdom (UK)]

TWA: 1 (mg(Fe)/m) from MSHA standard Consult local authorities for acceptable exposure limits.

 

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Solid powder. Deliquescent solid.)

Odor: Odorless.

Taste: Saline, Mild ferruginois taste

Molecular Weight: Not available.

Color: Brownish. Yellowish.

pH (1% soln/water): Not available.

Boiling Point: Not available.

Melting Point: Not available.

Critical Temperature: Not available.

Specific Gravity: 1.8 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility: Easily soluble in cold water.

Solubility in water: 25 g/100 ml @ 20 deg. C. Practically insoluble in alcohol.

 

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Excess heat, incompatible materials, light

Incompatibility with various substances: Not available.

Corrosivity: Not available.

Special Remarks on Reactivity:

Incompatible with iodides, acacia preparations, and tannins. Sensitive to light.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

 

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals:

LD50: Not available.

LC50: Not available.

Chronic Effects on Humans: Not available.

Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals:

Lethal Dose/Conc: LD [Rat] - Route: Oral; Dose: >2000 mg/kg

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects:

Skin: Contact may cause irritation or rash, particularly with moist skin.  Eyes: May cause eye irritation with redness, tearing, and abrasion. Inhalation: Inhalation of high concentrations of dust may cause nasal, throat or lung irritation. Symptoms may include coughing and wheezing.

Ingestion: Ingestion can produce gastrointestinal tract irritation with hypermotility, diarrhea.

Chronic Potential Health Effects: Eyes: Prolonged eye contact may cause a brownish discoloration of the eyes. Skin: Prolonged skin contact may cause skin irritation.

 

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.

Special Remarks on the Products of Biodegradation: Not available.

 

Section 13: Disposal Considerations

Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

 

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.

Special Provisions for Transport: Not applicable.

 

Section 15: Other Regulatory Information

Federal and State Regulations:

Connecticut hazardous material survey.: Ferric ammonium citrate Illinois chemical safety act: Ferric ammonium citrate New York release reporting list: Ferric ammonium citrate

Pennsylvania RTK: Ferric ammonium citrate Massachusetts RTK: Ferric ammonium citrate

Massachusetts spill list: Ferric ammonium citrate New Jersey: Ferric ammonium citrate

New Jersey spill list: Ferric ammonium citrate Louisiana spill reporting: Ferric ammonium citrate

TSCA 8(b) inventory: Ferric ammonium citrate CERCLA: Hazardous substances.: Ferric ammonium citrate: 1000 lbs. (453.6 kg)

Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada): Not controlled under WHMIS (Canada).

DSCL (EEC):

This product is not classified according

to the EU regulations.

Not applicable.

HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 1

Reactivity: 0

Personal Protection: E

National Fire Protection Association (U.S.A.):

Health: 1

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment: Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.

16. Other Information

Disclaimer: Nile Chemicals. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
 

 

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